Bis(2,2′-bi-1H-imidazole-κ2 N 3,N 3′)(thiocyanato-κN)copper(II) chloride
نویسندگان
چکیده
In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio-cyanate anion and four N atoms from two chealting biimidazole ligands. The thio-cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N-H⋯S and N-H⋯Cl hydrogen bonds.
منابع مشابه
Bis(2,2′-bi-1H-imidazole-κ2 N 3,N 3′)bis(dimethyl sulfoxide-κO)copper(II) bis(tetrafluoridoborate)
In the title copper(II) salt, [Cu(C(6)H(6)N(4))(2)(C(2)H(6)OS)(2)](BF(4))(2), the Jahn-Teller distorted octa-hedral coordination sphere of copper is formed from four 2,2'-bi-1H-imidazole N atoms and two dimethyl sulfoxide O atoms. The Cu atom lies on a center of inversion. N-H⋯O and N-H⋯F hydrogen bonds give rise to a one-dimensional structure. The BF(4) (-) anion is disordered over two sites i...
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